Combine all of the ingredients in a slow cooker.
Cover and cook on the high setting for about 3 -4 hours (Total time will vary based on ripeness of pear).
Stir occasionally.
When the pears have softened, remove the vanilla bean and the orange zest.
With a handheld immersion blender, process the pears until smooth. Alternatively, the cooked pears can be transferred to a food processor, pureed and transferred back to the slow cooker.
Set the slow cooker on low and cook for an additional 6-8 hours. The total time will depend on the total moisture of the fruit. The pear butter is done when there is no liquid that seeps out when a teaspoon of the butter is placed on a dish.
Ladle the pear butter into sterile canning jars. Always leave about ¼ inch of head space. Try to remove as many air bubbles as possible.
Seal with sterile lids and rings.
Process in a boiling water bath for 15 minutes.
Remove jars from the pot.
Allow to cool to room temperature.
Check the lids by pressing on the center of each seal. If it springs back, the jars need to be refrigerated. Otherwise, they can be stored in a cool dark place for about 1 year.
Once the jar is opened, it can be stored for about 3 weeks in the refrigerator.
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